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Infrared spectroscopy of Au+(CH4)n complexes and vibrationally-enhanced C–H activation reactions

Abstract:

A combined spectroscopic and computational study of gas-phase Au+(CH4) n (n = 3–8) complexes reveals a strongly-bound linear Au+(CH4)2 core structure to which up to four additional ligands bind in a secondary coordination shell. Infrared resonance-enhanced photodissociation spectroscopy in the region of the CH4 a 1 and t 2 fundamental transitions reveals essentially free internal rotation of the core ligands about the H4C–Au+–CH4 axis, with sharp spectral features assigned by comparison with ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1007/s11244-017-0868-z

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More from this funder
Name:
Engineering and Physical Sciences Research Council
Grant:
EP/L005913
Publisher:
Springer US
Journal:
Topics in Catalysis More from this journal
Volume:
61
Issue:
1-2
Pages:
81–91
Publication date:
2017-10-30
Acceptance date:
2017-10-13
DOI:
EISSN:
1572-9028
ISSN:
1022-5528
Keywords:
Pubs id:
pubs:738693
UUID:
uuid:fb199beb-5d8b-44ba-81db-69c89c18e4ea
Local pid:
pubs:738693
Deposit date:
2017-10-26

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