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[PtMe(iPr3P)2]+: A Pt(II) complex with an agostic interaction that undergoes C-H activation

Abstract:
The T-shaped Pt(II) complex [PtMe(iPr3P) 2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr 3P)(iPr2PCHMeCH2)][1-H-closo-CB 11Me11].

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Publisher copy:
10.1039/b410846a

Authors


Ingleson, MJ More by this author
Weller, AS More by this author
Journal:
Chemical Communications
Volume:
10
Issue:
21
Pages:
2398-2399
Publication date:
2004-11-07
DOI:
ISSN:
1359-7345
URN:
uuid:fae6eb46-39c3-4973-ac45-dea23a0f6c56
Source identifiers:
330967
Local pid:
pubs:330967
Language:
English

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