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Mononuclear and dinuclear complexes with a [Ru(tBu2PCH2CH2PtBu2)(CO)] core.

Abstract:

Thermolysis of solid [Ru(d(t)bpe)(CO)2Cl2](2, d(t)bpe =(t)Bu2PCH2CH2P(t)Bu2) under vacuum affords the five-coordinate complex [Ru(d(t)bpe)(CO)Cl2] (4), which was shown by X-ray crystallography to contain a weak remote agostic interaction. In solution, 4 can be readily trapped by CO, CH3CN or water to give [Ru(d(t)bpe)(CO)(L)Cl2](L = CO, 2; L = CH3CN, 6; L = H2O, 7). Reaction of 4 with AgOTf/H2O yields the tris-aqua complex [Ru(d(t)bpe)(CO)(H2O)3](OTf)2 (8), which has been structurally charact...

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Publication status:
Published

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Publisher copy:
10.1039/b415812a

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Whittlesey, MK More by this author
Pregosin, PS More by this author
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
3
Pages:
588-597
Publication date:
2005-02-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:fa6fae07-2805-44c4-a3a7-7d098553cf49
Source identifiers:
32969
Local pid:
pubs:32969
Language:
English

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