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Adaptive finite element simulation of chronoamperometry at microdisc electrodes

Abstract:
In this paper we shall introduce a transient finite element algorithm by considering the simplest problem of numerical simulation of the chronoamperometric current for an E reaction mechanism at a microdisc electrode. Such a numerical simulation is made difficult by the presence of a boundary singularity where the electrode meets the insulator (often known as the 'edge-effect') and by a time-singularity caused by the impulsive start of the experiment. We attempt to overcome these problems by using an adaptive finite element algorithm in

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Journal:
Electrochemistry Communications
Volume:
5
Issue:
7
Pages:
519-529
Publication date:
2003-07-01
URN:
uuid:f9d8630e-c9fd-4fab-9b59-5e1382806594
Local pid:
cs:4266

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