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THE ROLE OF INITIAL CONDITIONS IN ELEMENTARY GAS-PHASE PROCESSES INVOLVING INTERMEDIATE COMPLEXES

Abstract:

When doing experiments with large numbers of gaseous molecules, it is difficult to distinguish the behavior characteristic of specific sets of molecules from the behavior of the entire ensemble. In this paper, several experiments involving unimolecular and bimolecular reactions are discussed which address this issue. In all cases, the initial conditions are well characterized, and reactions occur via intermediates for which the potential energy surface (PES) has pronounced local minima and no...

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Publication status:
Published

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Publisher copy:
10.1021/j100278a012

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Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
90
Issue:
6
Pages:
1015-1027
Publication date:
1986-03-13
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
Language:
English
Pubs id:
pubs:42599
UUID:
uuid:f9b78cff-8d6a-41ba-b639-46a1affb128f
Local pid:
pubs:42599
Source identifiers:
42599
Deposit date:
2012-12-19

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