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Dicyanometallates as model extended frameworks.

Abstract:

We report the structures of eight new dicyanometallate frameworks containing molecular extra-framework cations. These systems include a number of hybrid inorganic−organic analogues of conventional ceramics, such as Ruddlesden−Popper phases and perovskites. The structure types adopted are rationalized in the broader context of all known dicyanometallate framework structures. We show that the structural diversity of this family can be understood in terms of (i) the charge and coordination prefe...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/jacs.5b13446

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Publisher:
America Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
138
Issue:
18
Pages:
5886-5896
Publication date:
2016-04-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:f9a5fca2-4c0a-4ae7-8882-3bb1f1d4b1b3
Source identifiers:
619540
Local pid:
pubs:619540
Language:
English

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