On the mechanism of d-f energy transfer in RuII/LnIII and OsII/LnIII dyads: Dexter-type energy transfer over a distance of 20 A.
We have used time-resolved luminescence methods to study rates of photoinduced energy transfer (PEnT) from [M(bipy)3]2+ (M=Ru, Os) chromophores to Ln(III) ions with low-energy f-f states (Ln=Yb, Nd, Er) in d-f dyads in which the metal fragments are separated by a saturated -CH2CH2- spacer, a p-C6H4 spacer, or a p-(C6H4)2 spacer. The finding that d-->f PEnT is much faster across a conjugated p-C6H4 spacer than it is across a shorter CH2CH2 spacer points unequivocally to a Dexter-type energy...Expand abstract
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