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Journal article

Unexpected features of stretched Si-H...Mo beta-agostic interactions.

Abstract:
Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant.
Publication status:
Published

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Publisher copy:
10.1039/b315517j

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Chemical communications (Cambridge, England)
Volume:
10
Issue:
8
Pages:
952-953
Publication date:
2004-04-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:f98d0202-3608-4003-8706-08ab3ebe4bfc
Source identifiers:
51182
Local pid:
pubs:51182
Language:
English

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