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EXCHANGE OF ORGANOIMIDO GROUPS AT A MONONUCLEAR TITANIUM CENTER AND A CRYSTALLOGRAPHIC EVALUATION OF THE RELATIVE STRUCTURAL INFLUENCES OF THE NBU(T), NC(6)H(4)ME-4 AND NC6H4NO2-4 LIGANDS

Abstract:
The tert-butylimido complex [Ti(NBut)Cl2(py)3] 1a (py = pyridine) undergoes exchange reactions of the NBut ligand with arylamines RNH2 to form the arylimido derivatives [Ti(NR)Cl2(py)3] (R = C6H4Me-4 1b, C6H4NO2-4 1c or C6H3Me2-2,6 1d); comparison of the crystal structures of 1a-1c gave a direct evaluation of N-substituent effects in d0, six-co-ordinated organoimido complexes.
Publication status:
Published

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Publisher copy:
10.1039/dt9950003743

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS More from this journal
Issue:
22
Pages:
3743-3745
Publication date:
1995-11-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
Language:
English
Pubs id:
pubs:51474
UUID:
uuid:f970999d-9d94-44e4-8d28-368cf82d26aa
Local pid:
pubs:51474
Source identifiers:
51474
Deposit date:
2012-12-19

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