Journal article
EXCHANGE OF ORGANOIMIDO GROUPS AT A MONONUCLEAR TITANIUM CENTER AND A CRYSTALLOGRAPHIC EVALUATION OF THE RELATIVE STRUCTURAL INFLUENCES OF THE NBU(T), NC(6)H(4)ME-4 AND NC6H4NO2-4 LIGANDS
- Abstract:
- The tert-butylimido complex [Ti(NBut)Cl2(py)3] 1a (py = pyridine) undergoes exchange reactions of the NBut ligand with arylamines RNH2 to form the arylimido derivatives [Ti(NR)Cl2(py)3] (R = C6H4Me-4 1b, C6H4NO2-4 1c or C6H3Me2-2,6 1d); comparison of the crystal structures of 1a-1c gave a direct evaluation of N-substituent effects in d0, six-co-ordinated organoimido complexes.
- Publication status:
- Published
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS More from this journal
- Issue:
- 22
- Pages:
- 3743-3745
- Publication date:
- 1995-11-21
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
0300-9246
- Language:
-
English
- Pubs id:
-
pubs:51474
- UUID:
-
uuid:f970999d-9d94-44e4-8d28-368cf82d26aa
- Local pid:
-
pubs:51474
- Source identifiers:
-
51474
- Deposit date:
-
2012-12-19
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- Copyright date:
- 1995
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