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Custom coordination environments for lanthanoids: tripodal ligands achieve near-perfect octahedral coordination for two dysprosium-based molecular nanomagnets

Abstract:

Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.inorgchem.6b03118

Authors


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Role:
Author
ORCID:
0000-0002-2277-3974
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Role:
Author
ORCID:
0000-0003-0204-9601
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Name:
Ministry of Economy and Competitiveness (MINECO), Spain
Grant:
MAT2014-56143-R
CTQ2014-52758-P
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Name:
European Union
Grant:
ERCCoG-647301
ERC-StG-338258
15128
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Name:
Korean Priority Research Centers Program
Grant:
NRF2010-0020209
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Name:
Korea Carbon Capture and Sequestration R and D Center (KCRC)
Grant:
NRF-2012-0008901
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Name:
Korean Basic Science Research Program
Grant:
NRF-2015R1A2A1A10055658
Publisher:
American Chemical Society
Journal:
Inorganic chemistry More from this journal
Volume:
56
Issue:
9
Pages:
4911-4917
Publication date:
2017-04-17
Acceptance date:
2017-04-12
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pmid:
28414438
Language:
English
Pubs id:
pubs:690796
UUID:
uuid:f7cc6612-a6ed-48fb-9011-49fc19c689f9
Local pid:
pubs:690796
Source identifiers:
690796
Deposit date:
2019-08-26

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