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A stable heavier group 14 analogue of vinylidene

Abstract:

Vinylidene (H2C=C) is a member of the family of compounds of composition CH (and isomeric with ethyne, HC≡CH), but it has been observed only transiently—with a lifetime in the region of 0.1 ns. Indeed, no simple (non-base-stabilized) compounds of the type R2E=E have been characterized structurally for any of the group 14 elements. Here we show that by employing the bulky and strongly electron-donating boryl ligand (HCDippN)2B (Dipp, 2,6-iPr2C6H3), a simple monomeric digermavinylidene compound...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1038/nchem.2597

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Grant:
Marie Curie IEF programme PIEF-GA-2013-622806
Publisher:
Nature Publishing Group Publisher's website
Journal:
Nature Chemistry Journal website
Volume:
8
Issue:
11
Pages:
1022–1026
Publication date:
2016-08-22
DOI:
EISSN:
1755-4349
ISSN:
1755-4330
Pubs id:
pubs:646387
URN:
uri:f6582e60-690e-41e1-b115-d58657f87ba4
UUID:
uuid:f6582e60-690e-41e1-b115-d58657f87ba4
Local pid:
pubs:646387
Paper number:
11

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