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On the variation of the structure of liquid deuterium fluoride with temperature.

Abstract:

The structure of liquid deuterium fluoride has been measured using pulsed neutron diffraction and high energy x-ray diffraction techniques as a function of temperature. The neutron experiments were performed at T=296+/-2 K, 246+/-2 K, and 193+/-2 K and the x-ray measurements carried out at 296+/-2 K and 195+/-2 K. The x-ray pair correlation functions, which are dominated by fluorine-fluorine interactions, show the first peak at approximately 2.53+/-0.05 A remains very nearly invariant with de...

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Publication status:
Published

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Publisher copy:
10.1063/1.1790432

Authors


Journal:
The Journal of chemical physics
Volume:
121
Issue:
13
Pages:
6448-6455
Publication date:
2004-10-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:f52da806-6dce-43ad-9fe2-349ea7fea460
Source identifiers:
196833
Local pid:
pubs:196833
Language:
English

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