Journal article
Mapping of N−C bond formation from a series of crystalline peri-substituted naphthalenes by charge density and solid-state NMR methodologies
- Abstract:
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A combination of charge density studies and solid state nuclear magnetic resonance (NMR) 1JNC coupling measurements supported by periodic density functional theory (DFT) calculations is used to characterise the transition from an n–π* interaction to bond formation between a nucleophilic nitrogen atom and an electrophilic sp2 carbon atom in a series of crystalline peri-substituted naphthalenes. As the N⋅⋅⋅C distance reduces there is a sharp decrease in the Laplacian derived from increasing cha...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, pdf, 2.2MB, Terms of use)
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- Publisher copy:
- 10.1002/anie.202111100
Authors
Funding
+ Engineering and Physical Sciences Research Council
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Grant:
EP/K000128/1
EP/M022501/1
EP/P022480/1
Bibliographic Details
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie International Edition More from this journal
- Volume:
- 60
- Issue:
- 44
- Pages:
- 23878-23884
- Place of publication:
- Germany
- Publication date:
- 2021-10-01
- Acceptance date:
- 2021-08-31
- DOI:
- EISSN:
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1521-3773
- ISSN:
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1433-7851
- Pmid:
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34464506
Item Description
- Language:
-
English
- Keywords:
- Pubs id:
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1193832
- Local pid:
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pubs:1193832
- Deposit date:
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2023-07-10
Terms of use
- Copyright holder:
- Rees et al
- Copyright date:
- 2021
- Rights statement:
- © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
- Licence:
- CC Attribution (CC BY)
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