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PHASE-SEPARATION IN METAL SOLUTIONS AND EXPANDED FLUID METALS

Abstract:

A most striking feature of concentrated metal-ammonia solutions (excluding cesium) is their separation into two liquid phases below a certain critical temperature (Tc; ca. -42°C for sodium-ammonia). Pitzer, over 20 years ago, suggested that this phenomenon in metal-ammonia solutions is the analogue within the liquid-ammonia matrix of the liquid-vapor separation that accompanies the cooling of a nonideal alkali metal vapor. In this communication we reexamine Pitzer's hypothesis in the light of...

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Publication status:
Published

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Publisher copy:
10.1021/ja00401a010
Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY More from this journal
Volume:
103
Issue:
11
Pages:
2967-2971
Publication date:
1981-01-01
DOI:
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:46404
UUID:
uuid:f46f1767-bc2f-418e-9f13-13e651930dcf
Local pid:
pubs:46404
Source identifiers:
46404
Deposit date:
2012-12-19

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