Journal article
PHASE-SEPARATION IN METAL SOLUTIONS AND EXPANDED FLUID METALS
- Abstract:
-
A most striking feature of concentrated metal-ammonia solutions (excluding cesium) is their separation into two liquid phases below a certain critical temperature (Tc; ca. -42°C for sodium-ammonia). Pitzer, over 20 years ago, suggested that this phenomenon in metal-ammonia solutions is the analogue within the liquid-ammonia matrix of the liquid-vapor separation that accompanies the cooling of a nonideal alkali metal vapor. In this communication we reexamine Pitzer's hypothesis in the light of...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY More from this journal
- Volume:
- 103
- Issue:
- 11
- Pages:
- 2967-2971
- Publication date:
- 1981-01-01
- DOI:
- ISSN:
-
0002-7863
Item Description
- Language:
-
English
- Pubs id:
-
pubs:46404
- UUID:
-
uuid:f46f1767-bc2f-418e-9f13-13e651930dcf
- Local pid:
-
pubs:46404
- Source identifiers:
-
46404
- Deposit date:
-
2012-12-19
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- Copyright date:
- 1981
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