Journal article
Synthesis and characterization of [Ru@Ge12]3-: an endohedral 3-connected cluster
- Abstract:
- The 12-vertex endohedral cluster [Ru@Ge12](3-) reveals an unprecedented D2d-symmetric 3-connected polyhedral geometry. The structure contrasts dramatically with the known deltahedral or approximately deltahedral geometries of [M@Pb12](2-) (M = Ni, Pd, Pt) and [Mn@Pb12](3-) and is a result of extensive delocalization of electron density from the transition-metal center onto the cage.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Preview, Accepted manuscript, 754.1KB, Terms of use)
-
- Publisher copy:
- 10.1021/ja411280v
Authors
+ Engineering and Physical Sciences Research Council
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- Grant:
- EP/D048559/1
- EP/F00186X/1
- EP/L011972/1
- EP/K021435/1
- Publisher:
- American Chemical Society
- Journal:
- Journal of the American Chemical Society More from this journal
- Volume:
- 136
- Issue:
- 4
- Pages:
- 1210-1213
- Place of publication:
- United States
- Publication date:
- 2014-01-14
- Acceptance date:
- 2013-12-30
- DOI:
- EISSN:
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1520-5126
- ISSN:
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0002-7863
- Pmid:
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24377744
- Language:
-
English
- Keywords:
- Pubs id:
-
445536
- Local pid:
-
pubs:445536
- Deposit date:
-
2020-07-30
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2014
- Rights statement:
- © 2013 American Chemical Society
- Notes:
- This is the accepted manuscript version of the article. The final version is available from ACS Publications at: https://doi.org/10.1021/ja411280v
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