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15R SrMn1-xFexO3-δ (x ≈ 0.1); A New Perovskite Stacking Sequence

Abstract:

A polycrystalline sample of a new phase in the Sr-Fe-Mn-O system has been prepared by standard solid-state techniques. Characterization at room temperature by X-ray diffraction, high-resolution electron microscopy, Mössbauer spectroscopy and neutron diffraction has led to it being described as a 15-layered, rhombohedral (15R) perovskite [space group R3̄m: a = 5.4489(1) Å, c = 33,8036(7) Å] with a previously unobserved structure. The pseudo close-packed SrO3 layers have a (cchch)3, stacking se...

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Publisher copy:
10.1021/ic980802j

Authors


Cussen, EJ More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Inorganic Chemistry
Volume:
37
Issue:
23
Pages:
6071-6077
Publication date:
1998
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:ef171d59-1ea5-466b-8267-99bf0d8c7277
Source identifiers:
125391
Local pid:
pubs:125391
Language:
English

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