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Rapid and efficient microwave-assisted Friedländer quinoline synthesis

Abstract:

A microwave‐based methodology facilitates reaction of 2‐aminophenylketones with cyclic ketones to form a quinoline scaffold. Syntheses of amido‐ and amino‐linked 17β‐hydroxysteroid dehydrogenase type 3 inhibitors with a benzophenone‐linked motif were pursued using 2‐aminobenzophenone as building block. Two amido‐linked targets were achieved in modest yield, but when using microwave‐assisted reductive amination for the amino‐linked counterparts an unexpected product was observed. X‐ray crystal...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/open.202000247

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Institution:
University of Oxford
Division:
MSD
Department:
Pharmacology
Role:
Author
ORCID:
0000-0003-3255-9135
Publisher:
Wiley Open Access
Journal:
ChemistryOpen More from this journal
Volume:
9
Issue:
11
Pages:
1113-1122
Publication date:
2020-11-05
Acceptance date:
2020-08-28
DOI:
EISSN:
2191-1363
Language:
English
Keywords:
Pubs id:
1135619
Local pid:
pubs:1135619
Deposit date:
2020-09-30

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