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Micellar catalysis for partial oxidation of toluene to benzoic acid in supercritical CO2: Effects of fluorinated surfactants

Abstract:

One of the key hindrances on development of solid catalysts containing cobalt species for partial oxidation of organic molecules at mild conditions in conventional liquid phase is the severe metal leaching. The leached soluble Co species with a higher degree of freedom always out-performs those of solid supported Co species in oxidation catalysis. However, the homogeneous Co species concomitantly introduces separation problems. We have recently reported for the first time, a new oxidation cat...

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Journal:
Catalysis Today
Volume:
81
Issue:
4
Pages:
673-679
Publication date:
2003-07-01
DOI:
ISSN:
0920-5861
URN:
uuid:edf29b2f-3d4d-4071-8e6b-e63a30baaf80
Source identifiers:
180233
Local pid:
pubs:180233

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