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A new composite electrode applied for studying the electrochemistry of insoluble particles: α-HgS

Abstract:

The redox chemistry of solid α-HgS particles is revealed using a carbon/PVDF composite containing α-HgS, carbon black, polyvinylidene fluoride (PVDF). The electrochemical behaviour of the carbon/PVDF composite is first characterised with three water insoluble organic solids. Then the reduction of solid α-HgS particles is investigated and found to occur at a high negative potential, -1.82V vs saturated mercury sulphate reference electrode, to form metallic mercury and sulphide ions. The subseq...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/chem.201801609

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More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Oxford college:
St John College
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Oxford college:
St Johns College
Publisher:
Wiley Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
24
Issue:
40
Pages:
10208-10215
Publication date:
2018-05-22
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:854519
URN:
uri:ea37bcae-c0a2-4ac4-be70-08d7dcc55a42
UUID:
uuid:ea37bcae-c0a2-4ac4-be70-08d7dcc55a42
Local pid:
pubs:854519

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