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The photodissociation dynamics of OCS at 248 nm: the S((3)P(J)) atomic angular momentum polarization.

Abstract:

The dissociation of OCS has been investigated subsequent to excitation at 248 nm using velocity map ion imaging. Speed distributions, speed dependent translational anisotropy parameters, and the atomic angular momentum orientation and alignment are reported for the channel leading to S((3)P(J)). The speed distributions and beta parameters are in broad agreement with previous work and show behavior that is highly sensitive to the S-atom spin-orbit state. The data are shown to be consistent wit...

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Publication status:
Published

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Publisher copy:
10.1063/1.2757619

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Quadrini, F More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
The Journal of chemical physics
Volume:
127
Issue:
8
Pages:
084305
Publication date:
2007-08-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:e7556fe8-5a5c-408b-8f97-14b38e84fbb4
Source identifiers:
33954
Local pid:
pubs:33954
Language:
English

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