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Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation

Abstract:
Reaction of [Ni(COD)2] with PEt3 and octafluoronaphthalene yielded the complex [Ni(η2-1,2-C10F8)(PEt3) 2] 1, which was converted thermally into the C - F activation product trans-[NiF(2-C10F7)(PEt3)2] 2. The crystal structure of 1 shows asymmetric η2 coordination with significant distortions of the naphthalene unit compared to the "free" ligand; DFT calculations reproduce the principal features of the geometry.
Publication status:
Published

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Publisher copy:
10.1039/b006368l

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Journal:
NEW JOURNAL OF CHEMISTRY
Volume:
25
Issue:
1
Pages:
19-21
Publication date:
2001-01-01
DOI:
EISSN:
1369-9261
ISSN:
1144-0546
URN:
uuid:e73bf48f-1ad0-4500-b712-12c154c5a790
Source identifiers:
50469
Local pid:
pubs:50469
Language:
English

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