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A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

Abstract:

The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6-host. The structural, electronic and magnetic features of the Cu6-complex, containing an endohedral fluoride in the rare μ6-F coordination mode, are compared with those of the parent complex with a vacant Cu6-cage.

Publication status:
Published
Peer review status:
Peer reviewed

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Role:
Author
ORCID:
0000-0002-3666-885X
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Role:
Author
ORCID:
0000-0002-8333-3868
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Role:
Author
ORCID:
0000-0002-5890-7874
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Name:
Engineering and Physical Sciences Research Council
Funder identifier:
http://dx.doi.org/10.13039/501100000266
Grant:
EP/G002789/2
Publisher:
Royal Society of Chemistry
Journal:
Dalton Transactions More from this journal
Volume:
44
Issue:
47
Pages:
20685-20691
Place of publication:
England
Publication date:
2015-11-04
Acceptance date:
2015-10-30
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Pmid:
26565718
Language:
English
Keywords:
Pubs id:
579432
Local pid:
pubs:579432
Deposit date:
2020-07-31

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