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[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain.

Abstract:
[Ni(HF(2))(3-Clpy)(4)]BF(4) (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN(4)F(2) octahedra that form chains with bridging HF(2)(-) ligands. In spite of significant distortion of the HF(2)(-) bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J(FHF) = 4.86 K.
Publication status:
Published

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Publisher copy:
10.1021/ic300111k

Authors


Manson, JL More by this author
Baldwin, AG More by this author
Del Sesto, RE More by this author
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Journal:
Inorganic chemistry
Volume:
51
Issue:
14
Pages:
7520-7528
Publication date:
2012-07-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:e608a2f4-4df8-4cbf-9b3a-254e2fe73df2
Source identifiers:
341052
Local pid:
pubs:341052
Language:
English

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