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REDOX-RESPONSIVE CROWN ETHERS CONTAINING A DIRECT LINK BETWEEN THE FERROCENE REDOX-ACTIVE CENTER AND A BENZO-CROWN ETHER - CRYSTAL-STRUCTURES OF A FERROCENE BENZO-15-CROWN-5 LIGAND AND OF IT SODIUM COMPLEX

Abstract:
The binding of Na+, K+ and Mg2+ to benzo-15-crown-5 and aza-15-crown-5 directly-linked ferrocenes results in shifts of the ferrocene oxidation wave to more positive potentials. The magnitude of these anodic shifts is related to the charge/radius ratio of the cationic guest. The results of an X-ray diffraction study of the structure of a ferrocene benzo-15-crown-5 sodium complex are also reported. © 1988.
Publication status:
Published

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Publisher copy:
10.1039/dt9900003295

Authors


SIKANYIKA, H More by this author
BLACKBURN, C More by this author
MCALEER, J More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Volume:
356
Issue:
11
Pages:
3295-3300
Publication date:
1990-11-05
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:e5f47166-8806-4420-9ea9-7766ac1ba9bd
Source identifiers:
46081
Local pid:
pubs:46081
Language:
English

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