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Journal article

The conformational analysis of phosphine ligands in organometallic complexes. Part 1. Triphenylphosphine coordinated to an achiral metal centre

Abstract:

The conformational analyses of PPh3 1 and the representative achiral metal complexes [Al(PPh3)(Me)3] 2, [Fe(PPh3)(CO)4] 7 and [Ir(PPh3)2(CO)3]+ 8 possessing tetrahedral and trigonal-bipyramidal geometries are reported, and comparisons between the calculated and solid-state structures are made. The intramolecular non-bonded interactions which govern the conformational preferences of PPh3 in both the free and complex-bound state are characterised. The equilibrium between the opposing inter ring...

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Publication status:
Published

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Publisher copy:
10.1039/a708014j

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
7
Pages:
1683-1689
Publication date:
1998-07-05
DOI:
EISSN:
1364-5471
ISSN:
0300-9580
URN:
uuid:e5ab6269-9205-4047-99c0-14c854f90f3c
Source identifiers:
110631
Local pid:
pubs:110631
Language:
English

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