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Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers.

Abstract:
Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1039/c2dt32009f

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry Research Laboratory
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Funding agency for:
Brown, A
Publisher:
Royal Society of Chemistry Publishing Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
42
Issue:
1
Pages:
67-70
Publication date:
2013-01-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:e5a53924-d3b0-4ca4-b78d-fac28fe5b0c7
Source identifiers:
358292
Local pid:
pubs:358292

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