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Imparting pH- and small molecule selectivity to nano-Pd catalysts via hydrothermal wrapping with chitosan

Abstract:

A nano-composite of negatively charged carbon nanoparticles (Emperor 2000™), chitosan, and nano-palladium is produced in a one-step hydrothermal process with oxalate reductant. In voltammetric measurements strong pH effects on capacitance and Faradaic current responses are observed due to chitosan forming a shell (or "hydrothermal wrapping") around both carbon nanoparticles and palladium particles in the water-based hydrothermal process. In spite of the wrapping, some Pd-catalytic processes a...

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Publisher copy:
10.1016/j.electacta.2013.01.014

Authors


Journal:
Electrochimica Acta More from this journal
Volume:
110
Pages:
663-669
Publication date:
2013-01-01
DOI:
ISSN:
0013-4686
Language:
English
Keywords:
Pubs id:
pubs:441565
UUID:
uuid:e56c2d32-032a-43bb-a9e4-90a8e041464d
Local pid:
pubs:441565
Source identifiers:
441565
Deposit date:
2014-02-10

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