Journal article
THE STEREOSPECIFIC SYNTHESIS OF (-)-(8R) AND (-)-(8S)-METHYLCANADINE
- Abstract:
-
Regioselective complexation of the dimethoxy arene ring of canadine to the Cr(CO)2 moiety gives two diastereoisomers which are separated by flash chromatography. Deprotonatlon of either diastereoisomer with n-butyllithium followed by addition of methyl iodide or trimethylsilyl chloride gives C11-methyl- or -trimethylsilylcanadine after decomplexatlon. Each diastereoisomer of the C11-trimethylsilylcanadine complex may be treated with base and methyl iodide to give, after desilylation and decom...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0040-4020(01)85104-8
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Bibliographic Details
- Journal:
- TETRAHEDRON
- Volume:
- 44
- Issue:
- 1
- Pages:
- 171-186
- Publication date:
- 1988-01-01
- DOI:
- ISSN:
-
0040-4020
- Source identifiers:
-
110803
Item Description
- Language:
- English
- Pubs id:
-
pubs:110803
- UUID:
-
uuid:e549d099-053e-44b7-9cac-b42f6ce254b1
- Local pid:
- pubs:110803
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1988
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