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A mechanism for non-stoichiometry in the lithium amide/lithium imide hydrogen storage reaction.

Abstract:
We demonstrate, through structural refinement from synchrotron X-ray diffraction data, that the mechanism of the transformation between lithium amide and lithium imide during hydrogen cycling in the important Li-N-H hydrogen storage system is a bulk reversible reaction that occurs in a non-stoichiometric manner within the cubic anti-fluorite-like Li-N-H structure.
Publication status:
Published

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Publisher copy:
10.1021/ja066016s

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Gregory, DH More by this author
Jewell, CM More by this author
Johnson, SR More by this author
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Journal:
Journal of the American Chemical Society
Volume:
129
Issue:
6
Pages:
1594-1601
Publication date:
2007-02-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:e529ab57-021a-486b-a7d3-49526ce2d09c
Source identifiers:
40220
Local pid:
pubs:40220
Language:
English

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