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The hydrogen-bonding transition and isotope-dependent negative thermal expansion in H3Co(CN)6.

Abstract:

We investigate the structures of H(3)Co(CN)(6) and D(3)Co(CN)(6) and their temperature dependence using a combination of advanced neutron and x-ray diffraction techniques. Lattice parameter refinements show marked temperature- and isotope-dependent effects in the thermal expansion behaviour. Reverse Monte Carlo modelling of neutron total scattering data characterizes the distribution of D atom positions in the deuterated compound; analysis of these distributions reveals that the two N-H/D bon...

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Publication status:
Published

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Authors


Goodwin, AL More by this author
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Journal:
Journal of physics. Condensed matter : an Institute of Physics journal
Volume:
22
Issue:
40
Pages:
404202
Publication date:
2010-10-05
DOI:
EISSN:
1361-648X
ISSN:
0953-8984
URN:
uuid:e4e93e78-46cb-4920-8194-99642556575e
Source identifiers:
83912
Local pid:
pubs:83912

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