Journal article icon

Journal article

Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10]

Abstract:

A new uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10] has been synthesized by a hydrothermal reaction technique using (C2H5)4NBr, UO2(OCOCH3)2·2H2O, and HF as reagents. The structure of [N(C2H5)4]2[(UO2)4(OH2)3F10] has been determined by a single-crystal X-ray diffraction technique. [N(C2H5)4]2[(UO2)4(OH2)3F10] crystallizes in the monoclinic space group P21/n (No. 14), with a = 13.852 (3) Å, b = 15.532 (3) Å, c = 16.481 (3) Å, β = 98.88 (3) °, V = 3503.4 (12) Å3, and Z = 4. [N(C2H5)4]2[(UO2)...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1016/j.jssc.2006.11.004

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
180
Issue:
2
Pages:
446-452
Publication date:
2007-02-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:e4b4414c-713a-4f3a-9109-554be418e584
Source identifiers:
51282
Local pid:
pubs:51282

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP