Journal article
Analytical solutions for the study of homogeneous first-order chemical kinetics via UV–vis spectroelectrochemistry
- Abstract:
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Analytical solutions are reported for the identification and study of homogeneous chemical reactions via UV-vis spectroelectrochemistry. Expressions are presented for the concentration profiles and the absorbance response of any the species of the CEC mechanism when applying a potential-pulse perturbation under semi-infinite linear diffusion conditions. With this theory it is possible to relate easily the absorbance transient to the physicochemical dynamics of the redox system. In particular,...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 1.3MB)
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- Publisher copy:
- 10.1016/j.jelechem.2017.10.031
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Authors
Funding
Spanish Ministry of Economics and Competitiveness
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Séneca Foundation
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Spanish Ministry of Education, Culture and Sport
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Bibliographic Details
- Publisher:
- Elsevier Publisher's website
- Journal:
- Journal of Electroanalytical Chemistry Journal website
- Volume:
- 819
- Pages:
- 202-213
- Publication date:
- 2017-10-16
- Acceptance date:
- 2017-10-14
- DOI:
- EISSN:
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1873-2569
- ISSN:
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1572-6657
- Source identifiers:
-
745702
Item Description
- Keywords:
- Pubs id:
-
pubs:745702
- UUID:
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uuid:e3e26d1a-d982-4908-af92-af94b0483093
- Local pid:
- pubs:745702
- Deposit date:
- 2018-04-11
Terms of use
- Copyright holder:
- Elsevier BV
- Copyright date:
- 2017
- Notes:
- © 2017 Elsevier B.V. All rights reserved. This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.jelechem.2017.10.031
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