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Asymmetric synthesis of beta-haloaryl beta-amino acid derivatives

Abstract:
Lithium N-benzyl-N-α-methyl-4-methoxybenzylamide may be employed as a homochiral ammonia equivalent for the synthesis of homochiral β-haloaryl β-amino acid derivatives via a strategy involving its conjugate addition to α,β-unsaturated β-haloaryl acceptors and subsequent oxidative deprotection with ceric ammonium nitrate.
Publication status:
Published

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Publisher copy:
10.1039/b108573p

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Delgado-Ballester, S More by this author
Kotchie, LJ More by this author
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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:
23
Pages:
3112-3121
Publication date:
2001
DOI:
EISSN:
1364-5463
ISSN:
1472-7781
URN:
uuid:e379cadb-bea0-4ca8-99b0-71f9ff1fb462
Source identifiers:
110593
Local pid:
pubs:110593
Language:
English

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