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Evolution of the structures and magnetic properties of the manganese dicarboxylates, Mn2(CO2(CH2)nCO 2)(OH)2 and Mn4(CO2(CH 2)nCO2)3(OH)2

Abstract:

Two new series of basic Mn dicarboxylate frameworks, Mn2(CO 2(CH2)nCO2)(OH)2 (where n = 0, 2, 4 and 5) and Mn4(CO2(CH2) nCO2)3(OH)2 (where n = 3 and 5), have been synthesised and the evolution of their structures with changing length of the dicarboxylate ligand was examined. Compounds in the Mn 2(CO2(CH2)nCO2)(OH) 2 series contain 2 dimensionally inorganically connected layers, which are bridged in the third dimension by the dicarboxylate ligand. While the compounds in this series with n = 0 ...

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Publisher copy:
10.1039/c1sc00253h

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Cheetham, AK More by this author
Journal:
Chemical Science
Volume:
2
Issue:
10
Pages:
1929-1939
Publication date:
2011-10-05
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
URN:
uuid:e350adb7-79d2-4c49-ab21-5c788bee2993
Source identifiers:
306632
Local pid:
pubs:306632
Language:
English

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