- Abstract:
-
Results of quantum calculations on rotationally and vibrationally inelastic scattering of S1 (1Ã) D2CO by He and Ar are presented. The azimuthal and vibrationally close-coupled, infinite-order sudden method is used. The extremely anharmonic ν4 bending mode of S1 D2CO is modelled using a double minimum potential. Large cross sections are predicted for collision-induced relaxation of the ν4 mode. Also, a large steric effect is predicted for energy transfer to this mode: collisions with the D2-e...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/0301-0104(92)87114-O
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- Journal:
- CHEMICAL PHYSICS
- Volume:
- 163
- Issue:
- 3
- Pages:
- 339-349
- Publication date:
- 1992-07-01
- DOI:
- ISSN:
-
0301-0104
- URN:
-
uuid:e335ebd5-c157-411b-a7de-656802e7b010
- Source identifiers:
-
53021
- Local pid:
- pubs:53021
- Language:
- English
- Copyright date:
- 1992
Journal article
ROTATIONALLY AND VIBRATIONALLY INELASTIC-SCATTERING OF 4(1) D2CO
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