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Synthesis, structure and properties of new iron-molybdenum and -tungsten fulvalene-bridged heterobimetallic complexes

Abstract:

Reaction of Li[C5H4Fe(C5H5)] with 2,3,4,5-tetramethylcyclopent-2-enone followed by acid work-up afforded the ferrocenyl-substituted cyclopentadiene [Fe(C5H5)(C5H4C5Me 4H)] 1. Lithiation of 1 with LiBun in hexane gave Li[C5Me4C5H4Fe(C5H 5)]. Reactions of this salt or the previously described lithium 3,4-dimethylcyclppentadienide or indenide homologues, Li[C5H2Me2C5H4Fe(C 5H5)] or Li[C9H6C5H4Fe(C5H 5)], with the allyl complexes [MoBr(MeCN)2(CO)2(η-C3H5)] or [WCl(MeCN)2(CO)2-(η-C3H5)] led to the...

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Publication status:
Published

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Publisher copy:
10.1039/dt9960001323

Authors


Begley, MJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Stewart, PJ More by this author
Swallow, D More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
7
Pages:
1323-1332
Publication date:
1996-04-07
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
URN:
uuid:e332a637-7c91-429c-8179-075037d268a4
Source identifiers:
51466
Local pid:
pubs:51466
Language:
English

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