Journal article

Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: evidence for solubilisation via a proton dissociation-recombination mechanism.

Abstract:: Quantitative Atomic Force Microscopy measurements made on the dissolving surface of solid salicylic acid in H2O and D2O reveal a kinetic isotope effect (kH/kD = 2.3 +/- 0.6) on the dissolution rate consistent with a transition state in which the proton is dissociated from the dissolving molecule.

Publication status:: Published

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APA Style

Wilkins, S., Coles, B., & Compton, R. (2002). Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: evidence for solubilisation via a proton dissociation-recombination mechanism. Chemical Communications, 7, 698–699.

MLA Style

Wilkins, S., et al. “Kinetic Isotope Effects on the Dissolution Kinetics of Solid Salicylic Acid in Aqueous Solution: Evidence for Solubilisation via a Proton Dissociation-Recombination Mechanism.” Chemical Communications, no. 7, 2002, pp. 698–99.

Chicago Style

Wilkins, S, B Coles, and R Compton. 2002. “Kinetic Isotope Effects on the Dissolution Kinetics of Solid Salicylic Acid in Aqueous Solution: Evidence for Solubilisation via a Proton Dissociation-Recombination Mechanism.” Chemical Communications, no. 7: 698–99.
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Publisher copy:: 10.1039/b111642h

Authors

+ Wilkins, S More by this author

Role:: Author

+ Coles, B More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: Chemical Communications More from this journal
Issue:: 7
Pages:: 698-699
Publication date:: 2002-04-01
DOI:: 10.1039/b111642h
EISSN:: 1364-548X
ISSN:: 1359-7345

Language:: English
Keywords:: Protons

Salicylic Acid

Microscopy, Atomic Force

Solubility

Deuterium

Water

Kinetics
Pubs id:: pubs:32149
UUID:: uuid:e2360967-61e9-4c37-83a5-f697b0687e51
Local pid:: pubs:32149
Source identifiers:: 32149
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2002

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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