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Synthesis, structural chemistry and magnetic properties of La(1+x)A(1-x)InMnO(6-delta): A = Ba, Sr; x = 0, 0.2

Abstract:

A series of novel double perovskites La1+xA1-xInMnO6-δ (A = Sr, Ba) has been prepared and the room temperature crystal structures have been refined using X-ray and neutron powder diffraction. In all cases the B-site is occupied by a disordered arrangement of In3+ and Mn3+/4+ cations. However, whereas La1+xBa1-xInMnO6-δ exhibits two octahedral tilts and exists in a body-centred cell, space group Imma, La1+xSr1-xInMnO6-δ adopts the three-tilt GdFeO3 structure and has a primitive orthorhombic st...

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Publication status:
Published

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Publisher copy:
10.1039/b100840o

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Jordan, NA More by this author
Rosseinsky, MJ More by this author
Singleton, J More by this author
Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
11
Issue:
6
Pages:
1656-1661
Publication date:
2001
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:e1cb23c2-550a-4dad-b87e-07029e29544b
Source identifiers:
37873
Local pid:
pubs:37873
Language:
English

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