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La3Ni2SbO9: a relaxor ferromagnet.

Abstract:

A polycrystalline sample of La3Ni2SbO9 has been synthesized using a standard ceramic method and characterized by neutron diffraction and magnetometry. The compound adopts a monoclinic, perovskite-like structure with space group P2(1)/n and unit cell parameters a = 5.0675(1), b = 5.6380(1), c = 7.9379(2) Å, β = 89.999(6)° at room temperature. The two crystallographically distinct six-coordinate sites are occupied by Ni(2+) and a disordered distribution of Ni(2+)/Sb(5+), respectively; the Ni(2+...

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Publication status:
Published

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Publisher copy:
10.1021/ic400675r

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Hunter, EC More by this author
Westwood, M More by this author
Journal:
Inorganic chemistry
Volume:
52
Issue:
11
Pages:
6648-6653
Publication date:
2013-06-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:e171b154-36e0-4ba7-a12c-00cc84b3af02
Source identifiers:
401828
Local pid:
pubs:401828
Language:
English

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