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Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes.

Abstract:

Addition of the new phosphonium carborane salts [HPR(3)][closo-CB(11)H(6)X(6)] (R = (i)Pr, Cy, Cyp; X = H 1a-c, X = Br 2a-c; Cy = C(6)H(11), Cyp = C(5)H(9)) to [Rh(nbd)(mu-OMe)](2) under a H(2) atmosphere gives the complexes Rh(PR(3))H(2)(closo-CB(11)H(12)) 3 (R = (i)Pr 3a, Cy 3b, Cyp 3c) and Rh(PR(3))H(2)(closo-CB(11)H(6)Br(6)) 4 (R = (i)Pr 4a, Cy 4b, Cyp 4c). These complexes have been characterised spectroscopically, and for 4b by single crystal X-ray crystallography. These data show that t...

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Publication status:
Published

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Publisher copy:
10.1039/b711468k

Authors


Molinos, E More by this author
Brayshaw, SK More by this author
Kociok-Köhn, G More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
42
Pages:
4829-4844
Publication date:
2007-11-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:e10d7a40-3aa2-449b-9576-ace6f494c564
Source identifiers:
40530
Local pid:
pubs:40530
Language:
English

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