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Anodic stripping voltammetry at a hydrodynamic mercury electrode under high mass transport conditions. 2. Experimental verification of theory and implications for sonovoltammetry

Abstract:

Anodic stripping voltammetry experiments were carried out in aqueous lead solution using square wave voltammetry at insonated mercury thin film electrodes and compared to numerical theory developed in an earlier paper (Ball, J. C.; Compton, R. G. J. Phys. Chem. B 1998, 102, 3967). Excellent agreement was obtained under very fast mass transport conditions corresponding to the small (∼micrometer) diffusion layer thickness obtained under power ultrasound. The results provide further confirmation...

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Publication status:
Published

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Publisher copy:
10.1021/jp982247c

Authors


Agra-Gutierrez, C More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B
Volume:
102
Issue:
36
Pages:
7028-7032
Publication date:
1998-09-03
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:e0a12b33-0e01-4309-97cb-94869b0f15df
Source identifiers:
36615
Local pid:
pubs:36615
Language:
English

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