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Electrochemical sizing of hemispherical microdroplets immobilized as regular arrays on partially blocked electrodes

Abstract:

The size of microdroplets of dodecane of approximately 5 μm diameter immobilised on a regular array of hydrophobic polymer blocks of a partially blocked electrode is determined by comparison of a simple electrochemical procedure with simulations. The electrochemical procedure is based on a simple Cottrellian-like potential-step experiment, where the current response is monitored as a function of time. Excellent agreement is found between theory and experiment thus giving physical support for ...

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Publication status:
Published

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Authors


Barnes, AS More by this author
Fietkau, N More by this author
Chevallier, FG More by this author
del Campo, J More by this author
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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
602
Issue:
1
Pages:
1-7
Publication date:
2007-04-01
DOI:
ISSN:
1572-6657
URN:
uuid:e04f74c8-6836-4546-b26b-27f70522f5af
Source identifiers:
40260
Local pid:
pubs:40260

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