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Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.

Abstract:
Chemical Equation Presented Cleared up! Intermolecular alkyne hydroacylation represents a new addition to the range of transition- metalcatalysed hydroacylation reactions that can be performed in an enantioselective manner. By using a kinetic resolution procedure, both racemic α- and βsubstituted aldehydes can be converted into the corresponding enantiomerically enriched substituted enone products (see scheme). © 2010 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/chem.201001748

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
16
Issue:
36
Pages:
10950-10954
Publication date:
2010-09-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Source identifiers:
67467
Language:
English
Keywords:
Pubs id:
pubs:67467
UUID:
uuid:dfe2179a-3726-43d2-a31a-9c4d64cbfec0
Local pid:
pubs:67467
Deposit date:
2012-12-19

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