- Abstract:
- Chemical Equation Presented Cleared up! Intermolecular alkyne hydroacylation represents a new addition to the range of transition- metalcatalysed hydroacylation reactions that can be performed in an enantioselective manner. By using a kinetic resolution procedure, both racemic α- and βsubstituted aldehydes can be converted into the corresponding enantiomerically enriched substituted enone products (see scheme). © 2010 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim.
- Publication status:
- Published
- Publisher copy:
- 10.1002/chem.201001748
-
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- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Volume:
- 16
- Issue:
- 36
- Pages:
- 10950-10954
- Publication date:
- 2010-09-05
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- URN:
-
uuid:dfe2179a-3726-43d2-a31a-9c4d64cbfec0
- Source identifiers:
-
67467
- Local pid:
- pubs:67467
- Language:
- English
- Keywords:
- Copyright date:
- 2010
Journal article
Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
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