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Synthesis, structures, and reactivity of two compounds containing the tancoite-like [Ga(HPO4)(2)F](2-)(infinity) chain

Abstract:

Compounds containing the one-dimensional macroanion [Ga(HPO4)2F]2- have been synthesized using ambient and moderate solvothermal conditions, and their interconversion and reactivity studied. The anionic chains exist in the hydrated gallium fluorophosphate (1) Ga(HPO4)2F·(NH3(CH2)3NH3)·2H2O, synthesized at room temperature from an aqueous reaction. Heating 1 in air at 70 °C gives the dehydrated form 2 or Ga(HPO4)2F·(NH3(CH2)3-NH3). 2 can also be solvothermally prepared at 120 °C from a water/D...

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Publication status:
Published

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Publisher copy:
10.1021/cm000195+

Authors


Walton, RI More by this author
Millange, F More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Loiseau, T More by this author
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Journal:
CHEMISTRY OF MATERIALS
Volume:
12
Issue:
7
Pages:
1977-1984
Publication date:
2000-07-05
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
URN:
uuid:df185305-7b5f-4359-90eb-91bfaf75a96f
Source identifiers:
51099
Local pid:
pubs:51099
Language:
English

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