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Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L-2)}(+) Fragments

Abstract:

Rhodium(III) dihydrido complexes [Rh(L2)(H)2(acetone) ][BArF4] (ArF = C6H 3(CF3)2) containing the potentially hemilabile ligands L2 = 9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene (Xantphos) and [Ph2P(CH2)2]2O (POP′) have been prepared from their corresponding norbornadiene rhodium(I) precursors. In solution these complexes are fluxional by proposed acetone dissociation, which can be trapped out by addition of MeCN to form [Rh(L2)(H)2(NCMe)][BArF4], which have been crystallographically char...

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Publication status:
Published

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Publisher copy:
10.1021/om9011104

Authors


Pawley, RJ More by this author
Moxham, GL More by this author
Dallanegra, R More by this author
Chaplin, AB More by this author
Brayshaw, SK More by this author
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Journal:
ORGANOMETALLICS
Volume:
29
Issue:
7
Pages:
1717-1728
Publication date:
2010-04-12
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:de81c74e-3730-4d87-9567-d1c1cf46551d
Source identifiers:
53351
Local pid:
pubs:53351
Language:
English

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