Journal article
Carbasugar-thioether pseudodisaccharides related to N-glycan biosynthesis.
- Abstract:
-
Analogues of the alpha-Glcp-(1-->3)-alpha-Glcp and alpha-Glcp-(1-->3)-alpha-Manp disaccharides (representing the two alpha-gluco linkages cleaved by alpha-Glucosidase II in N-glycan biosynthesis) in which the non-reducing-end sugar is replaced by a carbasugar and the inter-glycosidic oxygen by a sulfur were synthesised. The key coupling step was an S(N)2 displacement of an equatorial triflate at C-1 of the carbasugar by C-3 gluco or manno thiolates with inversion of configuration to giv...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/j.carres.2008.12.023
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Authors
Bibliographic Details
- Journal:
- Carbohydrate research
- Volume:
- 344
- Issue:
- 4
- Pages:
- 454-459
- Publication date:
- 2009-03-05
- DOI:
- EISSN:
-
1873-426X
- ISSN:
-
0008-6215
- URN:
-
uuid:de7bb8d9-b47f-4318-95c7-026c743f6cce
- Source identifiers:
-
101111
- Local pid:
- pubs:101111
Item Description
- Language:
- English
- Keywords:
Terms of use
- Copyright date:
- 2009
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