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Synthesis and ethylene trimerisation capability of new chromium(II) and chromium(III) heteroscorpionate complexes.

Abstract:

Reaction of (Me(2)pz)(2)CHSiMe(2)N(H)R (R = (i)Pr or Ph) or (Me(2)pz)(2)CHSiMe(2)NMe(2) with CrCl(3)(THF)(3) or CrCl(2)(THF)(2) gave Cr{(Me(2)pz)(2)CHSiMe(2)NR(1)R(2)}Cl(3) (R(1) = H, R(2) = (i)Pr (10) or Ph (11); R(1) = R(2) = Me (15)) or Cr{(Me(2)pz)(2)CHSiMe(2)NR(1)R(2)}Cl(2)(THF) (R(1) = H, R(2) = (i)Pr (12) or Ph (13); R(1) = R(2) = Me (16)), respectively. Compounds 10 and 11 were crystallographically characterized and the magnetic behaviour of all the new compounds was evaluated using S...

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Publication status:
Published

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Publisher copy:
10.1039/b926333k

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
39
Issue:
15
Pages:
3653-3664
Publication date:
2010-04-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:dcad038e-8ab7-40b7-8b80-ec8365ad9fe5
Source identifiers:
52607
Local pid:
pubs:52607
Language:
English

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