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Isomer-directed structural diversity and its effect on the nanosheet exfoliation and magnetic properties of 2,3-dimethylsuccinate hybrid frameworks.

Abstract:

The structures of seven new transition metal frameworks featuring Mn, Co, or Zn and either the meso or chiral D and L isomers of the 2,3-dimethylsuccinate ligand are reported. Frameworks that exhibit two-dimensional covalently bonded layers with weak interlayer interactions can be made with all three cations by incorporation of the chiral isomers of the 2,3-dimethylsuccinate ligand. The formation of such structures, suitable for the creation of nanosheets via exfoliation, is, however, not as ...

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Publication status:
Published

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Publisher copy:
10.1021/ic302011x

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Engineering Science
Role:
Author
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Journal:
Inorganic chemistry
Volume:
51
Issue:
20
Pages:
11198-11209
Publication date:
2012-10-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:dc83f75a-c9f0-4e93-8b77-75053140c170
Source identifiers:
354215
Local pid:
pubs:354215
Language:
English

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