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Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.

Abstract:
Square-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.
Publication status:
Published

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Publisher copy:
10.1021/ic202600n

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Journal:
Inorganic chemistry
Volume:
51
Issue:
4
Pages:
1989-1991
Publication date:
2012-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:dc3e5aa5-daec-4894-aeda-bd4d64baa191
Source identifiers:
245876
Local pid:
pubs:245876
Language:
English

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