- Abstract:
- Square-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.
- Publication status:
- Published
- Publisher copy:
- 10.1021/ic202600n
-
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- Journal:
- Inorganic chemistry
- Volume:
- 51
- Issue:
- 4
- Pages:
- 1989-1991
- Publication date:
- 2012-02-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:dc3e5aa5-daec-4894-aeda-bd4d64baa191
- Source identifiers:
-
245876
- Local pid:
- pubs:245876
- Language:
- English
- Copyright date:
- 2012
Journal article
Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.
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