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EXPERIMENTAL AND THEORETICAL-STUDIES OF THE F+H-2 TRANSITION-STATE REGION VIA PHOTOELECTRON-SPECTROSCOPY OF FH2-

Abstract:

The transition state region of the F+H2 reaction is studied by photoelectron spectroscopy of FH2 -. The photoelectron spectra consist of overlapping electronic bands with different angular distributions. The ground state band shows partially resolved features which differ depending on whether the anion is made from normal or para hydrogen. This dependence on the anion nuclear spin statistics implies that these features are due to progressions in bending levels of the neutral FH2 complex. In o...

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Publication status:
Published

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Publisher copy:
10.1063/1.465873

Authors


BRADFORTH, S More by this author
NEUMARK, D More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
99
Issue:
9
Pages:
6345-6359
Publication date:
1993-11-01
DOI:
ISSN:
0021-9606
URN:
uuid:dbe449f8-7b07-47c8-b8b5-bb275c0a1fd1
Source identifiers:
44237
Local pid:
pubs:44237

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